Mass spectrometric analysis of the reactivity of trityl cation

Show simple item record

dc.contributor.author Wei, Alan An Jung
dc.date.accessioned 2019-04-29T21:02:49Z
dc.date.available 2019-04-29T21:02:49Z
dc.date.copyright 2019 en_US
dc.date.issued 2019-04-29
dc.identifier.uri http://hdl.handle.net/1828/10792
dc.description.abstract Ever since its accidental discovery in the 70s, methylaluminoxane, MAO, has been a popular and widely used activator in olefin polymerization. Hydrolysis of primethylaluminum, Me3Al, produces MAO, an aluminum-, oxygen-, and methyl-containing oligomer. Polyolefins have become one of the most produced polymers, where MAO-activated single-site catalysts are responsible for the synthesis of polymers with highly defined structures. The detailed structure of MAO however, remains a mystery. In order to thoroughly understand the reactivity of MAO, knowing more about it is essential. Electrospray ionization mass spectrometry (ESI-MS) has proven to be a useful technique for studying catalysts and their activation chemistry. It has been shown that MAO is best thought of as a source for the highly reactive and Lewis acidic dimethylaluminum cation, [Me2Al]+. Synthetically, this ion is accessible via the reaction between trityl tetrakis(pentafluorophenyl)borate, [Ph3C]+[B(C6F5)4]- and trimethylaluminum, and this reaction was investigated in detail. A new reaction, substitution of H for CH3 onto the phenyl ring of the trityl carbocation, [Ph3C]+, was detected and found to be general for all trialkylaluminums studied. All instruments with detectors are prone to signal saturation at high concentration and mass spectrometers are no exception. Despite the advantages that ESI-MS offers, saturation can be one of the main obstacles in terms of the accurate quantification of species. This thesis tackles saturation issues in ESI-MS explicitly, because relatively high concentrations were necessary in order to keep unwanted decomposition reactions to a minimum. By detuning various parameters that allows troubleshooting this issue, data that better reflects the reality and the corresponding quantification of species is obtained. With the optimal settings of parameters, quantitative studies and the reactivity regarding the addition of trimethylaluminum, Me3Al, to the trityl carbocation [Ph3C]+ can be better understood. en_US
dc.language English eng
dc.language.iso en en_US
dc.rights Available to the World Wide Web en_US
dc.subject mass spectrometry en_US
dc.subject electrospray ionization en_US
dc.subject trityl en_US
dc.subject saturation en_US
dc.title Mass spectrometric analysis of the reactivity of trityl cation en_US
dc.type Thesis en_US
dc.contributor.supervisor McIndoe, J. Scott
dc.degree.department Department of Chemistry en_US
dc.degree.level Master of Science M.Sc. en_US
dc.description.scholarlevel Graduate en_US

Files in this item

This item appears in the following Collection(s)

Show simple item record

Search UVicSpace


My Account