Morris, Louis J.; Hill, Michael S.; Manners, Ian; McMullin, Claire L.; Mahon, Mary F.; Rajabi, Nasir A.
(Chemical Communications, 2019)
Reaction of the dimeric calcium hydride, [(BDI)CaH]2, with Ph3SnH ensues with elimination of H2 to provide [(BDI)Ca-μ2-H-(SnPh3)Ca(BDI)] and [(BDI)Ca(SnPh3)]2 alongside dismutation to Ph4Sn, H2 and Sn(0). DFT analysis ...