Calcium stannyl formation by organostannane dehydrogenation
Date
2019
Authors
Morris, Louis J.
Hill, Michael S.
Manners, Ian
McMullin, Claire L.
Mahon, Mary F.
Rajabi, Nasir A.
Journal Title
Journal ISSN
Volume Title
Publisher
Chemical Communications
Abstract
Reaction of the dimeric calcium hydride, [(BDI)CaH]2, with Ph3SnH ensues with elimination of H2 to provide [(BDI)Ca-μ2-H-(SnPh3)Ca(BDI)] and [(BDI)Ca(SnPh3)]2 alongside dismutation to Ph4Sn, H2 and Sn(0). DFT analysis indicates that stannyl anion formation occurs through deprotonation of Ph3SnH and with retention of dinuclear species throughout the reactions.
Description
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Citation
Morris, L. J., Hill, M. S., Manners, I., McMullin, C. L., Mary F. Mahon, M. F., & Rajabi, N. A. (2019). Calcium stannyl formation by organostannane dehydrogenation. Chemical Communications, 55(86). https://doi.org/10.1039/c9cc07289f