Optimization of growth conditions of GaAs1-xBix alloys for laser applications

dc.contributor.authorBahrami Yekta, Vahid
dc.contributor.supervisorTiedje, Thomas
dc.date.accessioned2016-04-07T14:50:26Z
dc.date.available2016-04-07T14:50:26Z
dc.date.copyright2016en_US
dc.date.issued2016-04-07
dc.degree.departmentDepartment of Electrical and Computer Engineering
dc.degree.levelDoctor of Philosophy Ph.D.en_US
dc.description.abstractGaAsBi is a relatively unexplored alloy with interesting features such as a large bandgap reduction for a given lattice mismatch with GaAs substrates and good photoluminescence which make it promising for long wavelength light detection and emission applications. In this research, the molecular beam epitaxy (MBE) method was used to grow epi-layers and hetero-structures. A Vertical-external-cavity surface-emitting-laser (VECSEL) was grown as a part of collaboration with Tampere University in Finland. The process of laser growth promoted the writer’s skills in the growth of hetero-structures and led into an investigation of the effect of growth conditions on GaAsBi optical properties with important results. For instance, when the substrate temperature during growth was reduced from 400°C to 300°C and all other growth conditions were fixed, the Bi concentration in the deposited films increased from 1% to 5% and the photoluminescence (PL) intensity decreased by more than a factor of 1000. This is an indication of the importance of growth temperature in GaAsBi crystal quality. n+/p junctions were grown for the deep level transient spectroscopy (DLTS) experiments in collaboration with Simon Fraser University. The DLTS measurements showed that lowering the GaAsBi growth temperature increases the deep level density by a factor of 10. These deep levels are the source of non-radiative recombination and decrease the PL intensity. The structural properties of GaAsBi were investigated by high resolution x-ray diffraction and polarized PL and revealed long distance atomic arrangement (Cu-Pt ordering) in GaAsBi. The measurements showed that the ordering is more probable at high growth temperature. This can be due to the larger mobility of the atoms on the surface at high growth temperatures that allows them to find the ordered low energy sites.en_US
dc.description.scholarlevelGraduateen_US
dc.identifier.bibliographicCitationMBE growth optimization for GaAs1− xBix and dependence of photoluminescence on growth temperature, Vahid Bahrami-Yekta, Thomas Tiedje, Mostafa Masnadi-Shirazi, Semiconductor Science and Technology (2015)en_US
dc.identifier.urihttp://hdl.handle.net/1828/7099
dc.languageEnglisheng
dc.language.isoenen_US
dc.rightsAvailable to the World Wide Weben_US
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/2.5/ca/*
dc.subjectMolecular Beam Epitaxyen_US
dc.subjectGaAsBien_US
dc.subjectSemiconductor laseren_US
dc.subjectUltra High vacuumen_US
dc.subjectcrystal defectsen_US
dc.titleOptimization of growth conditions of GaAs1-xBix alloys for laser applicationsen_US
dc.typeThesisen_US

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