Active magnetic regenerators: performance in the vicinity of para-ferromagnetic second order phase transitions

dc.contributor.authorRowe, Andrew Michael
dc.contributor.supervisorBarclay, John A.
dc.date.accessioned2018-11-02T21:46:36Z
dc.date.available2018-11-02T21:46:36Z
dc.date.copyright2002en_US
dc.date.issued2018-11-02
dc.degree.departmentDepartment of Mechanical Engineeringen_US
dc.degree.levelDoctor of Philosophy Ph.D.en_US
dc.description.abstractA technology that has the potential to liquefy hydrogen and natural gas efficiently is an Active Magnetic Regenerative Liquefier (AMRL). An AMRL exploits the magnetocaloric effect displayed by magnetic materials whereby a reversible temperature change is induced when the material is exposed to a magnetic field. This effect can be used to produce cooling. By using the magnetic materials in a regenerator as the heat storage medium and as the means of work input, one creates an Active Magnetic Regenerator (AMR). Because the adiabatic temperature change is a strong function of temperature for most materials, to span a large temperature range such as that needed to liquefy hydrogen, a number of different materials may be needed to make up one or more regenerators. Single material AMRs have been proven, but layering with more than one material has not. This thesis is a study of AMRs using magnetic refrigerants displaying second-order paramagnetic to ferromagnetic ordering. An analysis of AMR thermodynamics is performed and results are used to define properties of ideal magnetic refrigerants. The design and construction of a novel test apparatus consisting of a conduction-cooled superconducting solenoid and a reciprocating AMR test apparatus are described. A numerical model is developed describing the energy transport in an AMR. Experiments using Gd are performed and results are used to validate the model. A strong relationship between flow phasing is discovered and possible reasons for this phenomenon are discussed. Simulations of AMRs operating in unconventional modes such as at temperatures greater than the transition temperature reveal new insights into AMR behaviour. Simulations of two-material layered AMRs suggest the existence of a jump phenomenon occurring regarding the temperature span. These results are used to explain the experimental results reported by other researchers for a two-material AMR.en_US
dc.description.scholarlevelGraduateen_US
dc.identifier.urihttp://hdl.handle.net/1828/10248
dc.languageEnglisheng
dc.language.isoenen_US
dc.rightsAvailable to the World Wide Weben_US
dc.subjectRefrigerantsen_US
dc.subjectSuperconducting magnetsen_US
dc.subjectRegeneratorsen_US
dc.subjectPhase transitionsen_US
dc.titleActive magnetic regenerators: performance in the vicinity of para-ferromagnetic second order phase transitionsen_US
dc.typeThesisen_US

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