Fibre optic sensors for PEM fuel cells

dc.contributor.authorDavid, Nigel
dc.contributor.supervisorWild, Peter Martin
dc.contributor.supervisorDjilali, Nedjib
dc.date.accessioned2012-01-03T23:09:16Z
dc.date.available2012-01-03T23:09:16Z
dc.date.copyright2011en_US
dc.date.issued2012-01-03
dc.degree.departmentDepartment of Mechanical Engineering
dc.degree.levelDoctor of Philosophy Ph.D.en_US
dc.description.abstractFibre-optic sensing techniques for application in polymer electrolyte fuel cells (PEMFC) are presented in this thesis. Temperature, relative humidity (RH) and air-water two-phase flow sensors are developed and demonstrated based on optical fibre Bragg gratings (FBG). Bragg gratings offer the following characteristics that warrant their development for application in PEMFCs: small size, environmental compatibility and the possibility of multiplexed multi-parameter sensing. Contributions of this work are in novel sensor development and implementation strategies. Important installation design considerations include the sensor proximity to the catalyst layer, sensor strain relief and minimal bending of the fibre. With these considerations, the dynamic and steady-state performance of FBG temperature sensors distributed throughout the flow-field of a single cell PEMFC was validated with a co-located micro-thermocouple. In the development of FBGs for in situ measurement of relative humidity, a polyimide-coated FBG based RH sensor is presented with significantly improved response time and sensitivity over previously reported designs. The RH inside a PEMFC under transient operating conditions is monitored. Step increases in current induce significantly larger increases in RH near the outlet than near the inlet of the cell, and associated transients within the fuel cell are found on a time scale approaching the sensor response time. Finally, to complete the suite of FBG sensors for water management in PEMFCs, an evanescent field based FBG sensor embedded in a microchannel for the measurement of two-phase flow dynamics is presented. Using high speed video for validation, it is established that the novel sensor enables the measurement of droplet average velocity and size in flow regimes representative of an operating fuel cell.en_US
dc.description.scholarlevelGraduateen_US
dc.identifier.bibliographicCitationN. A. David, P. M. Wild, J. Hu, N. Djilali, In- bre Bragg grat- ing sensors for distributed temperature measurement in a polymer elec- trolyte membrane fuel cell, Journal of Power Sources 192 (2009) 376{380. doi:10.1016/j.jpowsour.2009.03.021.en_US
dc.identifier.bibliographicCitationN. A. David, P. M. Wild, J. Jensen, T. Navessin, N. Djilali, Simultaneous in situ measurement of temperature and relative humidity in a PEMFC using optical ber sensors, Journal of The Electrochemical Society 157 (8) (2010) B1173{ B1179. doi:10.1149/1.3436652.en_US
dc.identifier.urihttp://hdl.handle.net/1828/3783
dc.languageEnglisheng
dc.language.isoenen_US
dc.rights.tempAvailable to the World Wide Weben_US
dc.subjectPEM fuel cell
dc.subjectFiber Bragg grating
dc.subjectTemperature
dc.subjectRelative humidity
dc.subjectTwo-phase flow
dc.subjectInstitute for Integrated Energy Systems (IESVic)
dc.titleFibre optic sensors for PEM fuel cellsen_US
dc.typeThesisen_US

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