The role of off-axis hydrothermal systems as an oceanic potassium sink

dc.contributor.authorLaureijs, Christiaan Thomas
dc.contributor.supervisorCoogan, Laurence A. of Earth and Ocean Sciencesen_US of Philosophy Ph.D.en_US
dc.description.abstractInputs of the major element potassium into the ocean from rivers and on-axis high temperature hydrothermal systems have likely varied on geological timescales. Variable uptake of potassium into lavas altered in low-temperature, off-axis, hydrothermal systems could keep the potassium concentration in seawater within the narrow range (~9.5 to 11 mmol L-1) observed in the Phanerozoic. To test this hypothesis a better understanding of the timing of alteration, and of the role of changing environmental conditions on seawater/basalt reactions is required. The age of 69 samples of the secondary, potassium-rich, phyllosilicate mineral celadonite from lavas in the Troodos ophiolite were determined using Rb-Sr radiometric dating to test whether potassium uptake occurs within a specific time interval. Measurements used tandem quadrupole ICP-MS/MS. Combined with published radiometric ages the dataset revealed regional differences in the duration of celadonite formation in the Troodos ophiolite lavas. In one area, where significant hydrothermal sediments were deposited on the lavas, celadonite formed as much as ~40 Myr after the crust accreted, whereas in an area with rare hydrothermal sediments celadonite formation was largely limited to the first ~20 Myr after crustal accretion. These differences in duration of celadonite formation in the upper oceanic crust are interpreted as reflecting differences in distribution of hydrothermal sediments that act as a source of labile Fe that is needed for celadonite formation. To test if there are significant variations of duration and timing of celadonite formation on various scales in the upper oceanic crust I measured the first in-situ Rb-Sr ages of celadonite in lavas from DSDP and ODP drill cores. These ages show that ~80% of celadonite formed from pervasive fluid flow within the first ~20 Myr after the oceanic crust accreted. All celadonite ages roughly correlate with the cumulative heat flow removed from the oceanic lithosphere in the same time interval. In combination the >100 new celadonite ages presented here provide strong evidence that most celadonite forms in the first ~20 Myr after crustal accretion and environmental conditions could be significant in controlling potassium uptake. To determine whether the potassium sink from seawater into altered seafloor lavas varied over time I compile a dataset of the potassium content of lavas from DSDP and ODP drill cores (0 to 180 Myr age range). Estimates of the average potassium content of individual holes reveal that this varies with age. However, holes of similar age show a similar magnitude of variability to that which occurs over this time. To investigate the source of the variability of potassium in altered lavas I modelled the effects of bottom seawater temperature and pH using PHREEQC. The models indicate that if the fluid is in equilibrium with K-feldspar, Na-beidellite and calcite, an increase in bottom seawater temperature and/or decrease in pH would lead to the potassium concentration in the off-axis fluid to increase significantly. This emphasizes the need for future studies to investigate feedback mechanisms between low-temperature hydrothermal alteration in response to changing environmental conditions.en_US
dc.identifier.bibliographicCitationLaureijs, C.T., Coogan, L.A., Spence, J., 2021a. In-situ Rb-Sr dating of celadonite from altered upper oceanic crust using laser ablation ICP-MS/MS. Chem. Geol. 579, 120339.
dc.identifier.bibliographicCitationLaureijs, C.T., Coogan, L.A., Spence, J., 2021b. A high throughput Rb-Sr dating method using solution tandem ICP-MS/MS (87Sr/86Sr) and standard addition calibration ICP-MS (Rb/Sr). MethodsX 8, 101309.
dc.identifier.bibliographicCitationLaureijs, C.T., Coogan, L.A., Spence, J., 2021c. Regionally variable timing and duration of celadonite formation in the Troodos lavas (Cyprus) from Rb-Sr age distributions. Chem. Geol. 560, 119995.
dc.rightsAvailable to the World Wide Weben_US
dc.subjectOff-axis hydrothermal systemsen_US
dc.subjectRb-Sr datingen_US
dc.subjectthermodynamic modellingen_US
dc.subjectPotassium cycleen_US
dc.subjecttandem ICP-MS/MSen_US
dc.titleThe role of off-axis hydrothermal systems as an oceanic potassium sinken_US


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