Microfluidic self-assembly of quantum dot compound micelles
| dc.contributor.author | Schabas, Greg | |
| dc.contributor.supervisor | Sinton, David | |
| dc.date.accessioned | 2007-08-27T23:50:14Z | |
| dc.date.available | 2007-08-27T23:50:14Z | |
| dc.date.copyright | 2007 | en_US |
| dc.date.issued | 2007-08-27T23:50:14Z | |
| dc.degree.department | Department of Mechanical Engineering | |
| dc.degree.level | Master of Applied Science M.A.Sc. | en_US |
| dc.description.abstract | This thesis is devoted to the development of microfluidic processes for the controlled self-assembly of quantum dot compound micelles (QDCMs). Microfluidic processes are developed to combine the constituents (cadmium sulfide quantum dots, and block copolymer stabilizing chains) with water to facilitate self-assembly of the composite particles, QDCMs, through initial phase separation, subsequent growth, and eventual quenching. Two genres of microfluidic reactors are developed. The on-chip evolution of QDCM formation and growth is resolved through fluorescence microscopy; QDCM size distributions and associated statistics are determined through off-chip analysis by transmission electron microscopy (TEM). In a flow-focusing reactor, control over the mean size of QDCMs is demonstrated through both the water concentration and the growth time (or reactor channel length). Controlled QDCM self-assembly is also demonstrated in a multiphase gas-liquid reactor. In contrast to the flow-focusing reactor, increasing the multiphase reactor channel length results in a decrease in QDCM size and polydispersity. | en_US |
| dc.identifier.uri | http://hdl.handle.net/1828/206 | |
| dc.language | English | eng |
| dc.language.iso | en | en_US |
| dc.rights | Available to the World Wide Web | en_US |
| dc.subject | Microfluidics | en_US |
| dc.subject | Quantum Dots | en_US |
| dc.subject | Micelles | en_US |
| dc.subject.lcsh | UVic Subject Index::Sciences and Engineering::Engineering::Mechanical engineering | en_US |
| dc.title | Microfluidic self-assembly of quantum dot compound micelles | en_US |
| dc.type | Thesis | en_US |
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