Microfluidic self-assembly of quantum dot compound micelles

dc.contributor.authorSchabas, Greg
dc.contributor.supervisorSinton, David
dc.date.accessioned2007-08-27T23:50:14Z
dc.date.available2007-08-27T23:50:14Z
dc.date.copyright2007en_US
dc.date.issued2007-08-27T23:50:14Z
dc.degree.departmentDepartment of Mechanical Engineering
dc.degree.levelMaster of Applied Science M.A.Sc.en_US
dc.description.abstractThis thesis is devoted to the development of microfluidic processes for the controlled self-assembly of quantum dot compound micelles (QDCMs). Microfluidic processes are developed to combine the constituents (cadmium sulfide quantum dots, and block copolymer stabilizing chains) with water to facilitate self-assembly of the composite particles, QDCMs, through initial phase separation, subsequent growth, and eventual quenching. Two genres of microfluidic reactors are developed. The on-chip evolution of QDCM formation and growth is resolved through fluorescence microscopy; QDCM size distributions and associated statistics are determined through off-chip analysis by transmission electron microscopy (TEM). In a flow-focusing reactor, control over the mean size of QDCMs is demonstrated through both the water concentration and the growth time (or reactor channel length). Controlled QDCM self-assembly is also demonstrated in a multiphase gas-liquid reactor. In contrast to the flow-focusing reactor, increasing the multiphase reactor channel length results in a decrease in QDCM size and polydispersity.en_US
dc.identifier.urihttp://hdl.handle.net/1828/206
dc.languageEnglisheng
dc.language.isoenen_US
dc.rightsAvailable to the World Wide Weben_US
dc.subjectMicrofluidicsen_US
dc.subjectQuantum Dotsen_US
dc.subjectMicellesen_US
dc.subject.lcshUVic Subject Index::Sciences and Engineering::Engineering::Mechanical engineeringen_US
dc.titleMicrofluidic self-assembly of quantum dot compound micellesen_US
dc.typeThesisen_US

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