Simultaneous orthogonal methods for the real-time analysis of catalytic reactions

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dc.contributor.authorTheron, Robin
dc.contributor.authorWu, Y.
dc.contributor.authorYunker, Lars P.E.
dc.contributor.authorHesketh, Amelia V.
dc.contributor.authorPernik, Indrek
dc.contributor.authorWeller, Andrew S.
dc.contributor.authorMcIndoe, J. Scott
dc.date.accessioned2017-03-29T23:15:25Z
dc.date.available2017-03-29T23:15:25Z
dc.date.copyright2016en_US
dc.date.issued2016
dc.description.abstractContinuous monitoring of catalyzed reactions using infrared spectroscopy (IR) measures the transformation of reactant into product; while mass spectrometry delineates the dynamics of the catalytically-relevant species present at much lower concentrations, a holistic approach that provides mechanistic insight into reaction components whose abundance spans five orders of magnitude. Probing reactions to this depth reveals entities that include precatalysts, resting states, intermediates, and also catalyst impurities and decomposition products. Simple temporal profiles that arise from this analysis aid discrimination between the different types of species, and a hydroacylation reaction catalyzed by a cationic rhodium complex is studied in detail to provide a test case for the utility of this methodology.en_US
dc.description.reviewstatusRevieweden_US
dc.description.scholarlevelFacultyen_US
dc.description.sponsorshipNSERCen_US
dc.identifier.citationTheron, R., Wu, Y., Yunker, L. P. E., Hesketh, A. V., Pernik, I., Wellerb, A. S. & McIndoe, J. S. (2016). Simultaneous orthogonal methods for the real-time analysis of catalytic reactions. ACS Catalysis, 6(10), 6911-9617.en_US
dc.identifier.urihttp://hdl.handle.net/1828/7875
dc.identifier.urihttps://doi.org/10.1021/acscatal.6b01489
dc.language.isoenen_US
dc.publisherACS Catalysisen_US
dc.subjectmass spectrometry, infrared spectroscopy, real-time monitoring, catalysis, hydroacylation
dc.subject.departmentDepartment of Chemistry
dc.titleSimultaneous orthogonal methods for the real-time analysis of catalytic reactionsen_US
dc.typePostprinten_US

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