Prying open a Thiele cage: discovery of an unprecedented extended pinacol rearrangement

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dc.contributor.authorDao, Nathan
dc.contributor.authorSader, Jonathan K.
dc.contributor.authorOliver, Allen G.
dc.contributor.authorWulff, Jeremy E.
dc.date.accessioned2020-06-19T20:19:42Z
dc.date.available2020-06-19T20:19:42Z
dc.date.copyright2019en_US
dc.date.issued2019
dc.description.abstractThe first extended pinacol rearrangement across an sp3–sp3 bond is reported. The reaction appears to be both stereo- and regio-specific, and results in an extremely rare example of cage opening for a 1,3-bishomocubane structure derived from Thiele's ester.en_US
dc.description.reviewstatusRevieweden_US
dc.description.scholarlevelFacultyen_US
dc.description.sponsorshipWe acknowledge NSERC Canada for operating funds, and for a fellowship to J. S. We also thank the Canada Research Chairs Program, the Michael Smith Foundation for Health Research, and the University of Victoria for ongoing support.en_US
dc.identifier.citationDao, N., Sader, J. K., Oliver, A. G., & Wulff, J. E. (2019). Prying open a Thiele cage: Discovery of an unprecedented extended pinacol rearrangement. Chemical Communications, 55, 1600-1603. https://doi.org/10.1039/C8CC08862Den_US
dc.identifier.urihttps://doi.org/10.1039/C8CC08862D
dc.identifier.urihttp://hdl.handle.net/1828/11866
dc.language.isoenen_US
dc.publisherChemical Communicationsen_US
dc.subject.departmentDepartment of Chemistry
dc.titlePrying open a Thiele cage: discovery of an unprecedented extended pinacol rearrangementen_US
dc.typePostprinten_US

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