Relative binding affinities of fluorobenzene ligands in cationic rhodium bisphosphine η6-fluorobenzene complexes probed using collision-induced dissociation

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dc.contributor.authorPike, Sebastian D.
dc.contributor.authorPernik, Indrek
dc.contributor.authorTheron, Robin
dc.contributor.authorMcIndoe, J. Scott
dc.contributor.authorWeller, Andrew S.
dc.date.accessioned2018-05-30T17:47:55Z
dc.date.available2018-05-30T17:47:55Z
dc.date.copyright2015en_US
dc.date.issued2015
dc.description.abstractA range of cationic rhodium bisphosphine η6-fluorobenzene (fluorobenzenes = C6H6-nFn, n = 1-3) and related complexes have been synthesized and characterized. These complexes act as useful organometallic precursors for catalysis or further synthetic elaboration. The relative binding affinity of the arene ligands has been investigated using Electrospray Ionisation Mass Spectrometry (ESI-MS) and two different collision-induced dissociation (CID) techniques. The influence of arene fluorination upon arene binding affinity is discussed as well as the comparison of different bisephosphine ligands with regard to bite angle and phosphine substitution. We show that this simple technique allows fast and easy comparison of the binding affinity of arene ligands to cationic organometallic fragments.en_US
dc.description.reviewstatusRevieweden_US
dc.description.scholarlevelFacultyen_US
dc.description.sponsorshipThe EPSRC and the University of Oxford for funding (DTG and PhD Plus Doctoral Prize Award to SDP). The Royal Society for an International Collaboration Travel Grant (ASW JSM). NSERC, CFI and the University of Victoria for operational and infrastructural funding (JSM).en_US
dc.identifier.citationPike, S.D., Pernik, I., Theron, R., McIndoe, J.S. & Weller, A.S. (2015). Relative binding affinities of fluorobenzene ligands in cationic rhodium bisphosphine η6- fluorobenzene complexes probed using collision-induced dissociation. Journal of Organometallic Chemistry, 784, 75-83. http://dx.doi.org/10.1016/j.jorganchem.2014.08.012en_US
dc.identifier.urihttp://dx.doi.org/10.1016/j.jorganchem.2014.08.012
dc.identifier.urihttp://hdl.handle.net/1828/9407
dc.language.isoenen_US
dc.publisherJournal of Organometallic Chemistryen_US
dc.subjectMass spectrometryen_US
dc.subjectFluorobenzeneen_US
dc.subjectAreneen_US
dc.subjectRhodiumen_US
dc.subjectRelative binding affinityen_US
dc.titleRelative binding affinities of fluorobenzene ligands in cationic rhodium bisphosphine η6-fluorobenzene complexes probed using collision-induced dissociationen_US
dc.typeArticleen_US

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