Mechanistic insights from mass spectrometry: examination of the elementary steps of catalytic reactions in the gas phase

Simple item page
dc.contributor.authorVikse, Krista L.
dc.contributor.authorMcIndoe, J. Scott
dc.date.accessioned2017-04-24T17:41:09Z
dc.date.available2017-04-24T17:41:09Z
dc.date.copyright2015en_US
dc.date.issued2015
dc.description.abstractReal-time mass spectrometric monitoring of speciation in a catalytic reaction while it is occurring provides powerful insights into mechanistic aspects of the reaction, but cannot be expected to elucidate all details. However, mass spectrometers are not limited just to analysis: they can serve as reaction vessels in their own right, and given their powers of separation and activation in the gas phase, they are also capable of generating and isolating reactive intermediates. We can use these capabilities to help fill in our overall understanding of the catalytic cycle by examining the elementary steps that make it up. This article provides examples of how these simple reactions have been examined in the gas phase.en_US
dc.description.reviewstatusRevieweden_US
dc.description.scholarlevelFacultyen_US
dc.description.sponsorshipNSERC (Discovery and Discovery Accelerator Supplement)en_US
dc.identifier.citationVikse, K. L., & McIndoe, J. S. (2015). Mechanistic insights from mass spectrometry: Examination of the elementary steps of catalytic reactions in the gas phase. Pure and Applied Chemistry, 87(4), 361-377.en_US
dc.identifier.urihttp://dx.doi.org/10.1515/pac-2014-1118
dc.identifier.urihttp://hdl.handle.net/1828/7948
dc.language.isoenen_US
dc.publisherPure and Applied Chemistryen_US
dc.subject.departmentDepartment of Chemistry
dc.titleMechanistic insights from mass spectrometry: examination of the elementary steps of catalytic reactions in the gas phaseen_US
dc.typeArticleen_US

Files

Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
Vikse_Krista_PureAppChem_2015.pdf
Size:
4.17 MB
Format:
Adobe Portable Document Format
Description:
Article
Download
License bundle
Now showing 1 - 1 of 1
No Thumbnail Available
Name:
license.txt
Size:
1.74 KB
Format:
Item-specific license agreed upon to submission
Description:
Download

Collections

Faculty and Staff Publications
 
University of Victoria Libraries

We acknowledge and respect the Lək̓ʷəŋən (Songhees and Esquimalt) Peoples on whose territory the university stands, and the Lək̓ʷəŋən and W̱SÁNEĆ Peoples whose historical relationships with the land continue to this day.