Dynamic and Coverage Effects in EIS

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dc.contributor.authorHarrington, David A.
dc.date.accessioned2019-06-27T15:29:22Z
dc.date.available2019-06-27T15:29:22Z
dc.date.copyright2013en_US
dc.date.issued2013
dc.description.abstractThe effect of sweep rate on the validity of impedance measurements made dynamically when sweeping the potential is investigated by numerical solution of the differential equations for a simple adsorption reaction. The same method is used to show that dynamic EIS can detect a nucleation-growth-collision mechanism through a negative time constant, and that measurement in the unstable regime is possible, even though the data is not Kramers-Kronig transformable. The utility of the concept of the rate-determining step in EIS is demonstrated for a simple example.en_US
dc.description.reviewstatusRevieweden_US
dc.description.scholarlevelFacultyen_US
dc.description.sponsorshipI thank the Natural Sciences and Engineering Council of Canada and the University of Victoria for financial support of this work.en_US
dc.identifier.citationHarrington, D.A. (2013). Dynamic and Coverage Effects in EIS. ECS Transactions, 45(13), 3-14. http://dx.doi.org/10.1149/04513.0003ecsten_US
dc.identifier.urihttp://dx.doi.org/10.1149/04513.0003ecst
dc.identifier.urihttp://hdl.handle.net/1828/10942
dc.language.isoenen_US
dc.publisherECS Transactionsen_US
dc.subject.departmentDepartment of Chemistry
dc.titleDynamic and Coverage Effects in EISen_US
dc.typePostprinten_US

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