Are Methylaluminoxane Activators Sheets?
Date
2021
Authors
Collins, Scott
Hasan, Galib
Joshi, Anuj
McIndoe, J. Scott
Linnolahti, Mikko
Journal Title
Journal ISSN
Volume Title
Publisher
ChemPhysChem
Abstract
Density functional theory calculations on neutral sheet models for methylaluminoxane (MAO) indicate that these structures, containing 5-coordinate and 4-coordinate Al, are likely precursors to ion-pairs seen during the hydrolysis of trimethylaluminum (Me3Al) in the presence of donors such as octamethyltrisiloxane (OMTS). Ionization by both methide ([Me]−) and [Me2Al]+ abstraction, involving this donor, were studied by polarizable continuum model calculations in fluorobenzene (PhF) and o-difluorobenzene (DFB) media. These studies suggest that low MW, 5-coordinate sheets ionize by [Me2Al]+ abstraction, while [Me]− abstraction from Me3Al-OMTS is the likely process for higher MW 4-coordinate sheets. Further, comparison of anion stabilities per mole of aluminoxane repeat unit (MeAlO)n, suggest that anions such as [(MeAlO)7(Me3Al)4Me]−=[7,4]− are especially stable compared to higher homologues, even though their neutral precursors are unstable.
Description
Keywords
methylaluminoxane, ionization, ESI-MS, anionization, sheets, UVic Genome BC Proteomics Centre
Citation
Collins, S., Hasan, G., Joshi, A., McIndoe, J. S., & Linnolahti, M. (2021). Are Methylaluminoxane Activators Sheets? ChemPhysChem, 22(13), 1326-1335. https://doi.org/10.1002/cphc.202100268.