Calcium stannyl formation by organostannane dehydrogenation

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dc.contributor.authorMorris, Louis J.
dc.contributor.authorHill, Michael S.
dc.contributor.authorManners, Ian
dc.contributor.authorMcMullin, Claire L.
dc.contributor.authorMahon, Mary F.
dc.contributor.authorRajabi, Nasir A.
dc.date.accessioned2020-11-03T17:35:20Z
dc.date.available2020-11-03T17:35:20Z
dc.date.copyright2019en_US
dc.date.issued2019
dc.description.abstractReaction of the dimeric calcium hydride, [(BDI)CaH]2, with Ph3SnH ensues with elimination of H2 to provide [(BDI)Ca-μ2-H-(SnPh3)Ca(BDI)] and [(BDI)Ca(SnPh3)]2 alongside dismutation to Ph4Sn, H2 and Sn(0). DFT analysis indicates that stannyl anion formation occurs through deprotonation of Ph3SnH and with retention of dinuclear species throughout the reactions.en_US
dc.description.reviewstatusRevieweden_US
dc.description.scholarlevelFacultyen_US
dc.identifier.citationMorris, L. J., Hill, M. S., Manners, I., McMullin, C. L., Mary F. Mahon, M. F., & Rajabi, N. A. (2019). Calcium stannyl formation by organostannane dehydrogenation. Chemical Communications, 55(86). https://doi.org/10.1039/c9cc07289fen_US
dc.identifier.urihttps://doi.org/10.1039/c9cc07289f
dc.identifier.urihttp://hdl.handle.net/1828/12304
dc.language.isoenen_US
dc.publisherChemical Communicationsen_US
dc.subject.departmentDepartment of Chemistry
dc.titleCalcium stannyl formation by organostannane dehydrogenationen_US
dc.typeArticleen_US

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