Highly enantiodifferentiating site of human serum albumin for meditating photocyclodimerization of 2-anthracenecarboxylate elucidated by site-specific inhibition/quenching with xenon

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dc.contributor.authorNishijima, Masaki
dc.contributor.authorPace, Tamara C. S.
dc.contributor.authorBohne, Cornelia
dc.contributor.authorMori, Tadashi
dc.contributor.authorInoue, Yoshihisa
dc.contributor.authorWada, Takehiko
dc.date.accessioned2020-08-22T00:11:10Z
dc.date.available2020-08-22T00:11:10Z
dc.date.copyright2015en_US
dc.date.issued2015
dc.description.abstractComplementary to the previous assignment of the first, second, and fourth binding sites of human serum albumin (HSA) for 2-anthracenecarboxylate (AC) and the subsequent mediation of AC photocyclodimerization, the site-specific inhibition of the enantiodifferentiation by xenon allowed us to assign the remaining third and fifth AC-binding sites to subdomains IB and IIIB, respectively. This study reveals a clearer picture of the binding and photochirogenic behavior of HSA and further expands the scope of bio-supramolecular photochirogenesis.en_US
dc.description.reviewstatusRevieweden_US
dc.description.scholarlevelFacultyen_US
dc.description.sponsorshipThis work was supported by Grant-in-Aids for Challenging Exploratory Research (No. 25620163) from the Japan Society for the Promotion of Science (JSPS), Network Joint Research Center for Advanced Materials and Devices, Shorai Foundation for Science and Technology, and Sumitomo Foundation, all of which are gratefully acknowledged. The authors at UVic thank the Natural Sciences and Engineering Research Council of Canada (NSERC) for funding.en_US
dc.identifier.citationNishijima, M., Pace, T. C. S., Bohne, C., Mori, T., Inoue, Y., & Wada, T. (2015). Highly enantiodifferentiating site of human serum albumin for meditating photocyclodimerization of 2-anthracenecarboxylate elucidated by site-specific inhibition/quenching with xenon. Journal of Photochemistry and Photobiology A: Chemistry, 331, 89-94. https://doi.org/10.1016/j.jphotochem.2015.12.019.en_US
dc.identifier.urihttps://doi.org/10.1016/j.jphotochem.2015.12.019
dc.identifier.urihttp://hdl.handle.net/1828/12015
dc.language.isoenen_US
dc.publisherJournal of Photochemistry and Photobiology A: Chemistryen_US
dc.subjectPhotochirogenesis
dc.subject2-Anthracenecarboxylate
dc.subjectPhotocyclodimerization
dc.subjectHuman serum albumin
dc.subjectXenon
dc.subject.departmentDepartment of Chemistry
dc.titleHighly enantiodifferentiating site of human serum albumin for meditating photocyclodimerization of 2-anthracenecarboxylate elucidated by site-specific inhibition/quenching with xenonen_US
dc.typePostprinten_US

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